6533b830fe1ef96bd12972a4
RESEARCH PRODUCT
Approach Matters : The Kinetics of Interfacial Inverse-Electron Demand Diels-Alder Reactions
Digvijay GahtoryJudith FiretSidharam P. PujariHan ZuilhofHan ZuilhofHan ZuilhofJorge EscorihuelaRickdeb Sensubject
Reaction ratesKinetics010402 general chemistry01 natural sciencesCatalysisReaccions químiquesReaction rateChemical kineticsComputational chemistryOrganic chemistryInverse electron-demand Diels–Alder reactionDiels-Alder reactionCycloadditionDiels–Alder reactionVLAGMass spectrometry010405 organic chemistryChemistryCommunicationOrganic ChemistrySubstrate (chemistry)General ChemistryOrganische ChemieCommunicationsCycloaddition0104 chemical sciencesDiels–Alder reactionSurface modificationOrganic surface chemistryQuímica orgànicadescription
Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels Alder (IEDDA) reactions represent a promising metal-free candidate. Herein, we reveal quantitative surface functionalization within 15 min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained via a combination of XPS and surface-bound mass spectrometry (DART-MS).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | Chemistry-A European Journal |