6533b831fe1ef96bd12982a0

RESEARCH PRODUCT

Basic properties of the F-type centers in halides, oxides and perovskites

Eugene A. KotominEugene A. KotominJoachim MaierA.i. PopovA.i. Popov

subject

Nuclear and High Energy PhysicsColloidSingle electronChemistryInorganic chemistryHalidePhysical chemistryAlkali metalInstrumentationMetal colloidsCrystallographic defect

description

We present a short survey of the optical properties of primary radiation-induced point defects in alkali halides, simple oxides and some ABO3 perovskites. We discuss in details the optical properties of single electron F and F + centers in rock-salt (f.c.c.) alkali halides and oxides and show that the Mollwo–Ivey law well-known for the F-type centers in alkali halides may be extended for other rock-salt structure insulators. We also discuss the major differences in point defect production mechanisms in halides and oxides. We show that the Rabin–Klick diagram may be generalized for a whole family of alkali halides. The F-type center migration and aggregation into metal colloids in alkali halides and oxides is also discussed.

https://doi.org/10.1016/j.nimb.2010.05.053