6533b831fe1ef96bd1298579
RESEARCH PRODUCT
[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3P,C1,P′](trifluoroacetato)palladium(II)
Kari RissanenMario CetinaMarvin JohnsonOla F. Wendtsubject
Metal-Organic PapersChemistryHydrogen bondchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsBioinformaticspalladium ; pincer complexes ; hydrogen bonding ; X-ray structureCrystalCrystallographyAtomGeneral Materials ScienceChelationPalladiumdescription
The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra-molecular C-H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter-molecular C-H⋯O hydrogen bond, which self-assembles the mol-ecules into infinite chains parallel to the b axis.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-05-01 | Acta Crystallographica Section E Structure Reports Online |