6533b831fe1ef96bd1299116
RESEARCH PRODUCT
Partial aminomethylation of resorcarenes.
Kari RissanenMinna LuostarinenAlexander Shivanyuksubject
chemistry.chemical_compoundchemistryOrganic ChemistryOrganic chemistryDiisopropylamineResorcinolPhysical and Theoretical ChemistryResorcinareneBiochemistrydescription
Aminomethylation of resorcarenes at the wider rim with bulky diisopropylamine and formaline leads to trisubstituted derivatives. Analogous reaction with C(2v)-symmetrical resorcarene tetratosylate gives the monoaminomethylated compound. Further reactions of remaining unsubstituted resorcinol rings result in new resorcarene derivatives. [reaction: see text]
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-01-11 | Organic letters |