6533b831fe1ef96bd12996c4

RESEARCH PRODUCT

ChemInform Abstract: Iodine Oxidative Coupling of Diene- and Triene-Diolates of Unsaturated Carboxylic Acids.

Ramon MestresA. TortajadaMaría José AurellSalvador GilMargarita Parra

subject

chemistry.chemical_compoundDienechemistrychemistry.chemical_elementOxidative coupling of methaneGeneral MedicineIodineMedicinal chemistry

description

Abstract Oxidative Coupling of the dianions of unsaturated carboxylic acids 1 , and 4 with iodine, which provides a convenient and facile preparation of γ,γ and e,e-dicarboxylic acids 2 and 5, apparently occurs through SET substitution of intermediate iodo-carboxylates.

https://doi.org/10.1002/chin.199124110