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RESEARCH PRODUCT
Makrobicyclische Endorezeptoren: Synthese, Kristallstruktur und Einschluß organischer Gastmoleküle
Fritz VögtleIngo LüerKari Rissanensubject
chemistry.chemical_classificationChemistryLigandStereochemistrySupramolecular chemistryCrystal structureInclusion compoundInorganic Chemistrychemistry.chemical_compoundPolycyclic compoundPolymer chemistryMoleculeCyclophaneDichloromethanedescription
Macrobicyclic Endoreceptors: Synthesis, Crystal Structure, and Inclusion of Organic Guests The macrobicyclic ligand 2 is synthesized in a one-step cyclization procedure. According to an X-ray structure analysis three dichloromethane guest molecules are included inside the cavity, whereas water and methanol are found outside the cavity. The rigid endo preorganization of the nitrogen donors allows the complexation of three 2,9-disubstituted 1,10-phenanthrolines inside the cavity.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1992-08-01 | Chemische Berichte |