Biomimetic oxidation of pyrene and related aromatic hydrocarbons. Unexpected electron accepting abilities of pyrenequinones

6533b832fe1ef96bd129aeec

RESEARCH PRODUCT

Biomimetic oxidation of pyrene and related aromatic hydrocarbons. Unexpected electron accepting abilities of pyrenequinones

Enrique Ortí Alejandro López-moreno Francisco Bermejo Joaquín Calbo Atena Naeimi Atena Naeimi David Clemente-tejeda Emilio M. Pérez

subject

Electrons Electron Photochemistry Hydrocarbons Aromatic Catalysis Gas phase Catalysis chemistry.chemical_compound Biomimetics Materials Chemistry Organic chemistry Electrodes chemistry.chemical_classification Pyrenes Metals and Alloys Quinones Oxidation reduction General Chemistry Electron acceptor Benzoquinone Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Ceramics and Composites Pyrene Oxidation-Reduction Catalytic method

description

We present a mild catalytic method to oxidize PAHs and, in particular, pyrene. The pyrenediones are much better electron acceptors than benzoquinone in the gas phase and present similar accepting abilities in solution.

year	journal	country	edition	language
2014-07-10

10.1039/c4cc04026k http://hdl.handle.net/20.500.12614/554

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