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RESEARCH PRODUCT

Synthesis, characterization and crystal structures of polymeric and dimeric triphenyltin(IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl]phenyl}methylidene)amino]aryls

Eleonora RivarolaTushar S. Basu BaulAnthony LindenKeisham Surjit SinghRobert JiráskoMichal Holčapek

subject

LigandChemistryStereochemistryElectrospray ionizationOrganic ChemistryESI mass spectrometryCrystal structureBiochemistryMedicinal chemistryInorganic ChemistryTrigonal bipyramidal molecular geometrychemistry.chemical_compoundMössbauer spectroscopyMaterials ChemistryCarboxylatePhysical and Theoretical Chemistry

description

Abstract The triphenyltin(IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl]phenyl}methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H-, 13C-, 119Sn-NMR, ESI mass spectrometry, IR and 119mSn Mossbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of a representative carboxylate ligand (aryl = 4-CH3) and three Sn complexes, viz., polymeric (Ph3Sn[O2CC6H4{N N(C6H3-4-OH(C(H) NC6H4X-4))}-o])n (X = Me (1) and Br (2)) and dimeric (Ph3Sn[O2CC6H4{N N(C6H3-4-OH(C(H) NC6H4X-4))}-o])2 (X = OMe (4)) complexes are reported. The coordination environment in each complex is trigonal bipyramidal trans-Ph3SnO2. A single zwitterionic carboxylate ligand bridges adjacent Sn atoms via the carboxylate and phenoxide O atoms.

yearjournalcountryeditionlanguage
2005-10-01Journal of Organometallic Chemistry
https://doi.org/10.1016/j.jorganchem.2005.06.030