6533b833fe1ef96bd129c3ca

RESEARCH PRODUCT

Transition metal–saccharide chemistry: synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes

Erkki KolehmainenAbhijeet J. KarkamkarAnindita MukhopadhyayChebrolu P. Rao

subject

chemistry.chemical_classificationThermal AnalysisCircular dichroismSpectrometersStereochemistryCircular DichroismOrganic ChemistryMannoseFructoseGeneral MedicineXyloseBiochemistryAnalytical Chemistrychemistry.chemical_compoundchemistryTransition metalGalactoseRiboseOrganic chemistryMonosaccharideCyclic Voltammetry

description

Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, D-ribose and D-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO2 moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed.

10.1016/s0008-6215(98)00186-4https://igi.indrastra.com/items/show/51778