Search results for "Spectrometers"
showing 10 items of 29 documents
Commissioning of the vacuum system of the KATRIN Main Spectrometer
2016
The KATRIN experiment will probe the neutrino mass by measuring the β-electron energy spectrum near the endpoint of tritium β-decay. An integral energy analysis will be performed by an electro-static spectrometer (``Main Spectrometer''), an ultra-high vacuum vessel with a length of 23.2 m, a volume of 1240 m[superscript 3], and a complex inner electrode system with about 120 000 individual parts. The strong magnetic field that guides the β-electrons is provided by super-conducting solenoids at both ends of the spectrometer. Its influence on turbo-molecular pumps and vacuum gauges had to be considered. A system consisting of 6 turbo-molecular pumps and 3 km of non-evaporable getter strips ha…
Simulations on time-of-flight ERDA spectrometer performance
2016
The performance of a time-of-flight spectrometer consisting of two timing detectors and an ionization chamber energy detector has been studied using Monte Carlo simulations for the recoil creation and ion transport in the sample and detectors. The ionization chamber pulses have been calculated using Shockley-Ramo theorem and the pulse processing of a digitizing data acquisition setup has been modeled. Complete time-of-flight–energy histograms were simulated under realistic experimental conditions. The simulations were used to study instrumentation related effects in coincidence timing and position sensitivity, such as background in time-of-flight–energy histograms. Corresponding measurement…
Sun-induced chlorophyll fluorescence III: benchmarking retrieval methods and sensor characteristics for proximal sensing
2019
[EN] The interest of the scientific community on the remote observation of sun-induced chlorophyll fluorescence (SIF) has increased in the recent years. In this context, hyperspectral ground measurements play a crucial role in the calibration and validation of future satellite missions. For this reason, the European cooperation in science and technology (COST) Action ES1309 OPTIMISE has compiled three papers on instrument characterization, measurement setups and protocols, and retrieval methods (current paper). This study is divided in two sections; first, we evaluated the uncertainties in SIF retrieval methods (e.g., Fraunhofer line depth (FLD) approaches and spectral fitting method (SFM))…
Lanthanide–saccharide chemistry: synthesis and characterisation of Ce(III)–saccharide complexes
2000
A series of nine Ce(III) complexes has been synthesised with seven different monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, L-sorbose, D-ribose and D-xylose) and two different disaccharides (D-maltose and L-lactose), and these have been characterised with various analytical, spectral, magnetic and electrochemical techniques. The NMR studies have highlighted some interesting features about the metal-ion-binding pattern of the saccharides. Some additional coordination has been proposed along with the chelating groups in the saccharide molecules, based on the shifts in 13C NMR spectra. On the other hand, solution absorption studies and solid-state magnetic susceptibilities hav…
Line intensities of CH3D in the Triad region: 6–10μm
2004
Abstract Line intensities of the three lowest fundamentals of the 12CH3D Triad are modeled with an RMS of 3.2% using over 2100 observed values retrieved by multispectrum fitting of enriched sample spectra recorded with two Fourier transform spectrometers. The band strengths of the Triad in units of 10−18 cm−1/(molecule cm−2) at 296 K are, respectively, 2.33 for ν6 (E) at 1161 cm−1, 1.75 for ν3 (A1) at 1307 cm−1 and 0.571 for ν5 (E) at 1472 cm−1. The total calculated absorption arising from 12CH3D Triad fundamentals is 4.65×10−18 cm−1/(molecule cm−2) at 296 K. In addition, some 740 intensities of nine hotbands are fitted to 8.1%; most of the hotband measurements belong to 2ν6−ν6 and ν3+ν6−ν3…
Unveiling anion-induced folding in tripodal imidazolium receptors by ion-mobility mass spectrometry.
2021
The anion-induced folding of tripodal imidazolium receptors has been investigated by NMR spectroscopy, electrospray ionization ion mobility mass spectrometry and DFT calculations. Such folding can be switched by anion release upon collision induced dissociation.
A Geant4 simulation package for the sage spectrometer
2012
International audience; A comprehensive Geant4 simulation was built for the SAGE spectrometer. The simulation package includes the silicon and germanium detectors, the mechanical structure and the electromagnetic fields present in SAGE. This simulation can be used for making predictions through simulating experiments and for comparing simulated and experimental data to better understand the underlying physics.
Methane and carbon monoxide infrared emissions observed at the Canada-France-Hawaii Telescope during the collision of comet SL-9 with Jupiter
1995
Observations with the Fourier Transform Spectrometer were conducted in spectral ranges from 1.6 to 4.7 µm from July 17 to 21 (UT) on the hot plumes appearing on the limb as well as hours or days after the impacts. We present here an analysis of the methane emission observed at 3.3 µm some 10 min after the C impact, indicating the presence of a very small (less than 100 km wide) hot region with temperatures in the 750–1500 K range within the 0.1- to 0.01-mbar region. We also report the detection of CO emission at 4.7 µm 4.5 hrs after the L impact, indicative of a temperature of 274±10 K at the ∼1016 CO molec cm−2 level. The observations suggest that the stratospheric temperature decreases wi…
High resolution study of AsHD2: Ground state and the three bending fundamental bands v(3), v(4), and v(6)
2006
International audience; For the first time the infrared spectrum of the AsHD2 molecule has been measured in the region of the bending fundamental bands v(3), v(4), and v(6) on a Fourier transform spectrometer with a resolution of 0.0024 cm(-1) and analyzed. More than 5500 transitions with J(max) = 26 have been assigned and used both to obtain "ground state combination differences" and for the determination of upper state ro-vibrational energies of the triad (001000), (000100), and (000001). Rotational parameters including centrifugal distortion coefficients up to octic terms of the ground vibrational state were calculated by fitting more than 500 "ground state combination differences" with …
High-accuracy mass measurements on neutron deficient neon isotopes
2005
International audience; The atomic masses of the short-lived nuclides 17Ne and 19Ne have been measured with the triple-trap mass spectrometer ISOLTRAP at ISOLDE/CERN. The obtained mass excess for both nuclides deviates significantly from the literature value, in the case of 17Ne about 40 keV. The mass value of 17Ne can be applied for a test of the isobaric multiplet mass equation with respect to an isospin T = 3/2 quartet. In addition, both masses can contribute to the data analysis of collinear laser-spectroscopy experiments where mean-square nuclear-charge radii are determined.