6533b834fe1ef96bd129d744

RESEARCH PRODUCT

Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.

Belén Lerma-berlangaJavier Castells-gilCarolina R. GanivetNeyvis Almora-barriosJavier González-platasOscar FabeloNatalia M. PadialCarlos Marti-gastaldo

subject

Colloid and Surface Chemistry010405 organic chemistryGeneral Chemistry010402 general chemistry01 natural sciencesBiochemistryCatalysis0104 chemical sciences

description

Following the synthesis of hydroxamate titanium–organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium–organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g–1.

yearjournalcountryeditionlanguage
2021-12-08Journal of the American Chemical Society
10.1021/jacs.1c09278https://pubmed.ncbi.nlm.nih.gov/34877864