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Classification theory for anequilibrium phase transitions

Rudolf HilferRudolf Hilfer

subject

Phase transitionStatistical classificationScaling limitProbability theoryThermodynamic limitStatistical mechanicsLimit (mathematics)Statistical physicsSlowly varying functionMathematics

description

The paper introduces a classification of phase transitions in which each transition is characterized through its generalized order and a slowly varying function. This characterization is shown to be applicable in statistical mechanics as well as in thermodynamics albeit for different mathematical reasons. By introducing the block ensemble limit the statistical classification is based on the theory of stable laws from probability theory. The block ensemble limit combines scaling limit and thermodynamic limit. The thermodynamic classification on the other hand is based on generalizing Ehrenfest's traditional classification scheme. Both schemes imply the validity of scaling at phase transitions without the need to invoke renormalizaton-group arguments

https://doi.org/10.1103/physreve.48.2466