6533b834fe1ef96bd129d8a5

RESEARCH PRODUCT

Molecular coupling of light with plasmonic waveguides.

J. Jussi ToppariAnton KuzykHenrik KunttuTommi K. HakalaHanna TikkanenPäivi TörmäMika Pettersson

subject

DiffractionMaterials scienceFOS: Physical sciencesPhysics::Optics02 engineering and technology01 natural sciences7. Clean energyMicrometreOpticsPhysics - Chemical Physics0103 physical sciencesPolaritonPhysics::Chemical Physics010306 general physicsPlasmonChemical Physics (physics.chem-ph)business.industrySurface plasmonMolecular electronics021001 nanoscience & nanotechnologySurface plasmon polaritonAtomic and Molecular Physics and Optics0210 nano-technologybusinessExcitationOptics (physics.optics)Physics - Optics

description

We use molecules to couple light into and out of microscale plasmonic waveguides. Energy transfer, mediated by surface plasmons, from donor molecules to acceptor molecules over ten micrometer distances is demonstrated. Also surface plasmon coupled emission from the donor molecules is observed at similar distances away from the excitation spot. The lithographic fabrication method we use for positioning the dye molecules allows scaling to nanometer dimensions. The use of molecules as couplers between far-field and near-field light offers the advantages that no special excitation geometry is needed, any light source can be used to excite plasmons and the excitation can be localized below the diffraction limit. Moreover, the use of molecules has the potential for integration with molecular electronics and for the use of molecular self-assembly in fabrication. Our results constitute a proof-of-principle demonstration of a plasmonic waveguide where signal in- and outcoupling is done by molecules.

10.1364/oe.15.009908https://pubmed.ncbi.nlm.nih.gov/19547341