6533b834fe1ef96bd129dfa3

RESEARCH PRODUCT

Scalable heterogeneous synthesis of metallic nanoparticles and aggregates with polyvinyl alcohol

Kamal AbderrafiJosep Canet-ferrerRachid GradessRafael AbarguesJ. L. ValdesJuan P. Martínez-pastor

subject

ChemistryNanoparticleNanotechnologyColloidal silverGeneral ChemistryPolyvinyl alcoholCatalysislaw.inventionChemical kineticschemistry.chemical_compoundlawColloidal goldAgglomerateMaterials ChemistryMetal nanoparticlesFiltration

description

Here we report on a new route to synthesize colloidal silver and gold nanoparticles, potentially scalable for massive nanoparticle-production. This method is based on the microwave-assisted heterogeneous reduction of the metal salts with polyvinylalcohol. The reaction is carried out in alcohols, which are non-solvents for polyvinylalcohol. Nanoparticles can be very easily separated by filtration. The reaction kinetics are extremely fast. Size-controlled formation of nanoparticle agglomerates is accomplished with a seed-mediated synthesis of nanoparticles upon MW exposure.

https://doi.org/10.1039/b819027e