6533b834fe1ef96bd129dfa3
RESEARCH PRODUCT
Scalable heterogeneous synthesis of metallic nanoparticles and aggregates with polyvinyl alcohol
Kamal AbderrafiJosep Canet-ferrerRachid GradessRafael AbarguesJ. L. ValdesJuan P. Martínez-pastorsubject
ChemistryNanoparticleNanotechnologyColloidal silverGeneral ChemistryPolyvinyl alcoholCatalysislaw.inventionChemical kineticschemistry.chemical_compoundlawColloidal goldAgglomerateMaterials ChemistryMetal nanoparticlesFiltrationdescription
Here we report on a new route to synthesize colloidal silver and gold nanoparticles, potentially scalable for massive nanoparticle-production. This method is based on the microwave-assisted heterogeneous reduction of the metal salts with polyvinylalcohol. The reaction is carried out in alcohols, which are non-solvents for polyvinylalcohol. Nanoparticles can be very easily separated by filtration. The reaction kinetics are extremely fast. Size-controlled formation of nanoparticle agglomerates is accomplished with a seed-mediated synthesis of nanoparticles upon MW exposure.
year | journal | country | edition | language |
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2009-01-01 | New Journal of Chemistry |