6533b835fe1ef96bd129e94e

RESEARCH PRODUCT

Crystallization and melting of fractions of branched polyethylene

E. MaderekGert Strobl

subject

Materials sciencePolymers and PlasticsDispersitytechnology industry and agricultureIsothermal crystallizationPolyethylenelaw.inventionCondensed Matter::Soft Condensed MatterCondensed Matter::Materials ScienceLow-density polyethylenechemistry.chemical_compoundColloid and Surface ChemistryChemical engineeringchemistrylawCondensed Matter::SuperconductivityMaterials ChemistryPhysical and Theoretical ChemistryCrystallization

description

Effects of the molecular weight on the crystallization behaviour of branched polyethylene become observable if isothermal crystallization is studied at temperatures near to the melting end. Crystallinities decrease with decreasing molecular weight. Thicknesses of lamellae grown during isothermal crystallization are independent of the molecular weight. They depend only on temperature. Compared to the effect of the branches polydispersity gives only a minor contribution to the broadening of the crystallization and melting range of low density polyethylene.

https://doi.org/10.1007/bf01419830