6533b835fe1ef96bd129f381

RESEARCH PRODUCT

Isobaric vapor–liquid equilibria for the binary systems 1-propyl alcohol+dipropyl ether and 1-butyl alcohol+dibutyl ether at 20 and 101.3kPa

Estela LladosaRosa MuñozJuan B. MontónM.c. Burguet

subject

Activity coefficientUNIQUACChemistryGeneral Chemical EngineeringGeneral Physics and AstronomyThermodynamicsEtherDibutyl etherchemistry.chemical_compoundBoiling pointAzeotropeNon-random two-liquid modelBinary systemPhysical and Theoretical Chemistry

description

Abstract Isobaric vapor–liquid equilibrium measurements for the binary systems 1-propyl alcohol + dipropyl ether and 1-butyl alcohol + dibutyl ether are reported at 20 and 101.3 kPa. Both systems, which deviate positively from ideal behavior present a minimum boiling point azeotrope at both pressures, showing the azeotropic compositions a strong dependency on pressure. The activity coefficients and boiling points of the solutions were correlated with its composition by the Wilson, UNIQUAC, NRTL, and Wisniak–Tamir equations.

yearjournalcountryeditionlanguage
2006-09-01Fluid Phase Equilibria
https://doi.org/10.1016/j.fluid.2006.06.017