6533b835fe1ef96bd129fde4

RESEARCH PRODUCT

Study of inks on paper engravings using portable EDXRF spectrometry

Jorgelina CarballoJ.l. LluchClodoaldo RoldánJosé Lorenzo FerreroD. JuanesM. ArdidJefferson Ricardo PereiraR. Vives

subject

Nuclear and High Energy PhysicsMaterials scienceNondestructive analysisMineralogyMass spectrometryInstrumentation

description

Abstract The prints are fragile and delicate art objects that need for its examination a suitable technique for “in situ”, non-destructive and rapid analyses. The energy dispersive X-ray Fluorescence (EDXRF) spectrometry with portable instrumentation offers these analytical properties. In this work we present the EDXRF analyses of eight engravings elaborated with different techniques (etching and heliogravure) from the 17th to 20th centuries. The characterization of the paper is directly done from its EDXRF spectra, whereas the inks are characterized by the ink plus paper analysis after subtracting the background from the paper spectrum. Inorganic components of the paper engravings and inks have been identified from the EDXRF spectra and the results are discussed. Also, we present EDXRF analyses for the identification of inorganic components from six samples of modern inks.

https://doi.org/10.1016/s0168-583x(03)01694-x