6533b835fe1ef96bd129fdf2

RESEARCH PRODUCT

Theory of orientational glasses models, concepts, simulations

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Abstract This review describes the various attempts to develop a theoretical understanding for ordering and dynamics of randomly diluted molecular crystals, where quadrupole moments freeze in random orientations upon lowering the temperature, as a result of randomness and competing interactions. While some theories attempt to model this freezing into a phase with randomly oriented quadrupole moments in terms of a bond-disorder concept analogous to the Edwards-Anderson model of spin glasses, other theories attribute the freezing to random field-like terms in the Hamiltonian. While models of the latter type have been studied primarily by microscopic molecular field-type treatments, the former models have been treated both in the Sherrington-Kirkpatrick-Parisi infinite-range limit, and in the short-range case. Among the surprising findings of these treatments we emphasize the first-order glass transition (though lacking a latent heat) of the infinite-range Potts glass, the suggestion that the short-range Pot...