6533b836fe1ef96bd12a0bfc

RESEARCH PRODUCT

Unprecedented coexistence of cyano-bridged Mn4(III)Cr(III) and Mn2(III)Cr(III) heterobimetallic complexes in one single crystal.

Luminita Marilena TomaFrancesc LloretCatalina Ruiz‐pérezMiguel JulveDiana VisinescuOscar Fabelo

subject

Inorganic ChemistryCrystallographyChemistryAntiferromagnetismSingle crystalMagnetic field

description

The penta-[{MnIII(4-MeO-salen)(H2O)(micro-CN)}4CrIII(CN)2]+ and trinuclear [{MnIII(4-MeO-salen)(H2O)(micro-CN)}2CrIII(CN)4](-) units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.

yearjournalcountryeditionlanguage
2008-12-17Dalton transactions (Cambridge, England : 2003)
10.1039/b816412fhttps://pubmed.ncbi.nlm.nih.gov/19081969