6533b836fe1ef96bd12a1190

RESEARCH PRODUCT

Photostimulable energy transfer in doped nanostructures of alkali halides

G. Vâle

subject

PhotoluminescencePhotostimulated luminescenceChemistryExcitonDopingBiophysicsMineralogyHalideGeneral ChemistryCondensed Matter PhysicsAlkali metalBiochemistryElectron transport chainAtomic and Molecular Physics and OpticsChemical physicsCrystallite

description

Abstract In nanostructures of doped alkali halides, unrelaxed H-centres produced in the exciton decay are able to escape from the surface thus producing in the grains of polycrystalline film an excess concentration of F-centres, which has a great tendency to form an interacting F-centre chain or a canal. Role of this F-centre chain in photostimulable energy transfer is analysed. It is concluded that specific interaction of unrelaxed H-centres and electrons with the F-centre chain (or the canal) leads to the temperature-independent exciton or electron transport at any distance. Hence, the temperatureindependent photostimulated luminescence (PSL) response production and retrieval are experimentally observed.

https://doi.org/10.1016/s0022-2313(97)00242-1