A Co36Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine

6533b837fe1ef96bd12a1d0f

RESEARCH PRODUCT

A Co36Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine

Eva Rentschler Pablo Alborés Pablo Alborés

subject

media_common.quotation_subject CLUSTER COMPOUNDS Ciencias Químicas COBALT DICARBOXYPYRAZINE General Chemistry Art MAGNETIC PROPERTIES Química Inorgánica y Nuclear Humanities CIENCIAS NATURALES Y EXACTAS Catalysis media_common

description

A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact. Fil: Alborés, Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Johannes Gutenberg Universitat Mainz; Alemania Fil: Rentschler, Eva. Johannes Gutenberg Universitat Mainz; Alemania

year	journal	country	edition	language
2009-11-06	Angewandte Chemie International Edition

https://doi.org/10.1002/anie.200904743

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