6533b837fe1ef96bd12a1d57
RESEARCH PRODUCT
Crystal structure oftrans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate
Matti HaukkaBandar A. BabgiNaser Eltaher EltayebJamal Lasrisubject
crystal structureNitrileInorganic chemistrychemistry.chemical_elementCrystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesMedicinal chemistryNitronechemistry.chemical_compoundGeneral Materials ScienceN—O bond cleavageta116cycloadditionBond cleavagenitronechemistry.chemical_classificationCrystallographynitrileChemistryHydrogen bondGeneral ChemistrypalladiumcycloadditionCondensed Matter PhysicsCycloaddition0104 chemical sciencesQD901-999AcetamidePalladiumdescription
The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of thetrans-[dichlorido-bis(2,5,5-trimethyl-5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by twotrans-arranged chloride anions and a nitrogen atom from each of the two neutral organic ligands. In the crystal, N—H...O, O—H...O and O—H...Cl hydrogen bonds link complex molecules into double layers parallel to thebcplane.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-03-17 | Acta Crystallographica Section E Crystallographic Communications |