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RESEARCH PRODUCT
Temperature dependent properties of environmentally important synthetic musks.
Jaakko PaasivirtaDag BromanYngve ZebührSeija SinkkonenAnna-lea Rantalainensubject
Air PollutantsChromatographyVolatilisationChemical PhenomenaChemistryVapor pressureChemistry PhysicalHealth Toxicology and MutagenesisAnalytical chemistryTemperatureGeneral MedicinePollutionHigh-performance liquid chromatographyHenry's lawPartition coefficientFatty Acids MonounsaturatedLiquid stateEnvironmental ChemistryGas chromatographySolubilityVolatilizationdescription
Environmental fate determining physical properties including their temperature dependence for five nitro musks and for seven polycyclic musks were estimated. The properties evaluated were vapor pressure in a solid and liquid state (PS and PL), solubility in water (S), Henry's law coefficient (H = PL/S) and log octanol-water partition coefficient (log KOW). Gas chromatography for starting values of vapor pressure estimation and HPLC experiments at 5-20 degrees C for comparison of the theoretical versus experimental solubilities in water were performed. The values of temperature (T) dependence coefficients (Ai and Bi) in equations: log (Property)i = Ai - Bi/T were determined. Values of properties were compared with literature-based data, and an example of their use in environmental hazard estimation by fate modeling was given.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-10-24 | Environmental science and pollution research international |