6533b837fe1ef96bd12a1fe1
RESEARCH PRODUCT
Radical salts of TTF derivatives with the metal-metal bonded [Re2Cl8]2- anion
Hanhua ZhaoCarlos J. Gómez-garcíaKim R. DunbarEric W. ReinheimerEric W. ReinheimerJosé Ramón Galán-mascarósMarc Fourmiguésubject
Ttf derivativesChemistryOrganic ChemistryStacking02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesAnalytical ChemistryIonInorganic ChemistrySolventCrystallographyMolecule[CHIM]Chemical SciencesMetal metal0210 nano-technologySpectroscopyComputingMilieux_MISCELLANEOUSdescription
Abstract Four new salts of the radical cations of TMTSF (tetramethyltetraselenafulvalene), TMTTF (tetramethyltetrathiafulvalene), BEDT-TTF (bisethylenedithiotetrathia-fulvalene) (ET) and o-Me2TTF (o-4,4′-dimethyltetrathiafulvalene) with the metal–metal bonded dianion [Re2Cl8]2− were synthesized, and their structures and physical properties investigated. The structures of these semiconducting salts feature one-dimensional stacking of the donor molecules interleaved with [Re2Cl8]2− anions and interstitial solvent molecules.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-11-01 |