ChemInform Abstract: Mukaiyama-Michael Reactions with trans-2,5-Diarylpyrrolidine Catalysts: Enantioselectivity Arises from Attractive Noncovalent Interactions, Not from Steric Hindrance.

6533b837fe1ef96bd12a260f

RESEARCH PRODUCT

ChemInform Abstract: Mukaiyama-Michael Reactions with trans-2,5-Diarylpyrrolidine Catalysts: Enantioselectivity Arises from Attractive Noncovalent Interactions, Not from Steric Hindrance.

Gokarneswar Sahoo Petri M. Pihko Bianka Kótai Andrea Hamza Eeva K. Kemppainen A. Piisola Imre Pápai

subject

Steric effects chemistry.chemical_classification Addition reaction Chemistry Organocatalysis Enantioselective synthesis Non-covalent interactions General Medicine Combinatorial chemistry Catalysis

description

The 2,5-diphenylpyrrolidine-catalyzed enantioselective Mukaiyama—Michael reaction between substituted furans and enals is studied.

year	journal	country	edition	language
2014-10-02	ChemInform

https://doi.org/10.1002/chin.201442019

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