6533b837fe1ef96bd12a26f4

RESEARCH PRODUCT

Electrochemical chiral recognition by microparticle coatings of Pd complexes with bridging cyclometalated phosphines

Antonio DoménechDirk PennoIgor O. KoshevoyM. A. Ubeda

subject

ChemistryGeneral Chemical EngineeringInorganic chemistrychemistry.chemical_elementMetallacycleElectrochemistryElectrocatalystChlorideMetalchemistry.chemical_compoundvisual_artPolymer chemistryElectrochemistryvisual_art.visual_art_mediummedicineAnion bindingPhosphinemedicine.drugPalladium

description

Abstract The palladium(II) dinuclear complex with bridging cyclometalated phosphines, {Pd2[μ-(C6H4)PPh2]2(μ-O2CCH3)2} (Pd2L2), having a paddlewheel structure, is reversibly oxidized in CH2Cl2 to a dinuclear palladium(III) analogue via two successive one-electron steps. Solid state voltammetry of Pd2L2 in contact with aqueous electrolytes produce as one-electron oxidation with two competing mechanisms involving anion intercalation/anion binding between/to metal centres, chloride ions acting as inhibitors for the first pathway. R- and S-Pd2L2 produces a significant stereoselective electrocatalytic activity with respect to the oxidation of l - and d -glutamic acid in alkaline media.

yearjournalcountryeditionlanguage
2008-03-01Electrochimica Acta
https://doi.org/10.1016/j.electacta.2007.12.004