6533b837fe1ef96bd12a3014

RESEARCH PRODUCT

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Helmut RingsdorfHans-werner SchmidtKarl-heinz Dr EtzbachHeinz Eilingsfeld

subject

chemistry.chemical_compoundMonomerchemistryLiquid crystalCovalent bondLiquid crystallinePolymer chemistryCopolymerDichroic glassAnthraquinoneCharacterization (materials science)

description

Liquid-crystalline copolymers with covalently attached dichroic dyes were synthesized and characterized. Copolymers with high anthraquinone and trisazo-dye content were obtained by copolymerization of dye monomers with 4-cyanophenyl 4-(6-acryloyloxyhexyloxy)benzoate (1) and 6-acryloyloxyhexyl 4-(trans-4-propylcyclohexyl)benzoate (2). Particular attention is given to the influence of the dye content and the dye structure on the liquid-crystalline behavior of the copolymers.

https://doi.org/10.1002/macp.1987.021880611