6533b837fe1ef96bd12a31e3
RESEARCH PRODUCT
Electrocatalytic Behavior of Tetrathiafulvalene (TTF) and Extended Tetrathiafulvalene (exTTF) [FeFe] Hydrogenase Mimics
Carmen Ramírez De ArellanoCarmen Ramírez De ArellanoAlba ColladoAlejandro TorresMar Gómez-gallegoMiguel A. Sierrasubject
Cultural StudiesHistoryHydrogenaseLiterature and Literary TheoryChemistryFerredoxin HydrogenaseDithiol-Iron(III)-Sulphide ComplexOrganic chemistryQuímicaCombinatorial chemistrychemistry.chemical_compoundQD241-441ComplexTetrathiafulvaleneInorganic chemistryQD146-197description
TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes are able to interact with PAHs. In the absence of air and in acid media an electrocatalytic dihydrogen evolution reaction (HER) occurs, similarly to analogous [(μ-S2)Fe2(CO)6] complexes. However, in the presence of air, the TTF and exTTF organic moieties strongly influence the electrochemistry of these systems. The reported data may be valuable in the design of [FeFe] hydrogenase mimics able to combine the HER properties of the [FeFe] cores with the unique TTF properties
year | journal | country | edition | language |
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2021-09-13 | ACS Organic & Inorganic Au |