6533b837fe1ef96bd12a33e5
RESEARCH PRODUCT
A Chiral, Photoluminescent, and Spin-Canted {Cu(I)Re(IV)2}n Branched Chain.
Salah-eddine StiribaMiguel JulveGiovanni De MunnoDonatella ArmentanoJosé Martínez-lilloJuan FausFrancisco R. Fortea-pérezFrancesc Lloretsubject
Inorganic ChemistryCrystallographychemistry.chemical_compoundPhotoluminescencechemistryChain (algebraic topology)PyrazineCoordination polymerStereochemistryPhysical and Theoretical ChemistryMolecular systemsSpin (physics)description
A new heteroleptic 1D Cu(I)-Re(IV) coordination polymer of the formula {Cu(I)Re(IV)Cl4(μ-Cl)(μ-pyz)[Re(IV)Cl4(μ-bpym)]}n·nMeNO2 (1; pyz = pyrazine, bpym = 2,2'-bipyrimidine) has been prepared through the Cu(I)-mediated self-assembly of two different Re(IV) metalloligands, namely, [ReCl5(pyz)](-) and [ReCl4(bpym)]. 1 consists of chiral branched chains with an overall rack-type architecture displaying photoemission and magnetic ordering. These results constitute a first step toward making new multifunctional magnetic materials based on mixed 3d-5d molecular systems.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-05-07 | Inorganic chemistry |