6533b837fe1ef96bd12a33e7
RESEARCH PRODUCT
DOMAIN AND MOLECULAR SUPERLATTICE STRUCTURE OF DODECANETHIOL SELF-ASSEMBLED ON AU(111)
Christoph GerberHeon KangHeon KangH.-j. GüntherodtHelmut RingsdorfAlexis BaratoffDario AnselmettiBruno MichelHeiko WolfEmmanuel Delamarchesubject
CrystallographySuperstructureMaterials scienceSuperlatticeMonolayerDomain (ring theory)MicroscopyGeneral Physics and AstronomyMoleculeNanotechnologyQuantum tunnellingSelf assembleddescription
Annealed organic monolayers of dodecanethiol (CH3(CH2)11SH) self-assembled on Au(111) have been investigated by scanning tunnelling microscopy. By using very high tunnelling resistances (TOMEGA) we find evidence of well-ordered molecular domains at room temperature and observe two different types of c(4 x 2) superlattice structures with the same rectangular unit cell. In contrast to theoretical calculations each unit cell contains four inequivalent molecules. Possible reasons for this discrepancy are discussed.
year | journal | country | edition | language |
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1994-08-10 |