6533b837fe1ef96bd12a33e7

RESEARCH PRODUCT

DOMAIN AND MOLECULAR SUPERLATTICE STRUCTURE OF DODECANETHIOL SELF-ASSEMBLED ON AU(111)

Christoph GerberHeon KangHeon KangH.-j. GüntherodtHelmut RingsdorfAlexis BaratoffDario AnselmettiBruno MichelHeiko WolfEmmanuel Delamarche

subject

CrystallographySuperstructureMaterials scienceSuperlatticeMonolayerDomain (ring theory)MicroscopyGeneral Physics and AstronomyMoleculeNanotechnologyQuantum tunnellingSelf assembled

description

Annealed organic monolayers of dodecanethiol (CH3(CH2)11SH) self-assembled on Au(111) have been investigated by scanning tunnelling microscopy. By using very high tunnelling resistances (TOMEGA) we find evidence of well-ordered molecular domains at room temperature and observe two different types of c(4 x 2) superlattice structures with the same rectangular unit cell. In contrast to theoretical calculations each unit cell contains four inequivalent molecules. Possible reasons for this discrepancy are discussed.

10.1209/0295-5075/27/5/006https://doi.org/10.1209/0295-5075/27/5/006