6533b837fe1ef96bd12a33fe

RESEARCH PRODUCT

Combined SANS and SAXS experiments in polyolefins-hydrogenated oligocyclopentadiene (HOCP) blends

Alessandro TrioloJ. S. LinRoberto Triolo

subject

Statistics and ProbabilityMaterials scienceSmall-angle X-ray scatteringbusiness.industryScatteringSpinodal decompositionThermodynamicsCondensed Matter PhysicsSmall-angle neutron scatteringOpticsLamellar structureHigh-density polyethylenePolymer blendbusinessPhase diagram

description

Abstract Lamellar morphology in semicrystyalline polymer blends (iPP/HOCP and HDPE/HOCP) is investigated by means of Small Angle X-ray Scattering (SAXS) and Small Angle Neutron Scattering (SANS). The investigated blends present a complex phase diagram, as they show a miscibility gap. SAXS scattering curves of blends lying outside the miscibility gap can be analysed in the frame of the psuedo two phase model. In order to describe the complex morphology of blends lying inside the miscibility gap, the SANS technique revealed necessary. In this paper a novel method to describe the morphology of these complex systems by means of SANS is presented.

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