6533b838fe1ef96bd12a3a4e
RESEARCH PRODUCT
Organotin(IV) Complexes of Aromatic Acid Hydrazides: Preparation and Spectroscopic Studies
Swarnali Basu BaulEleonora RivarolaTushar S. Basu Baulsubject
DenticityAromatic acidLigandInorganic chemistrychemistry.chemical_elementInorganic ChemistrychemistryAtomOctahedral molecular geometryPolymer chemistryMössbauer spectroscopyChelationPhysical and Theoretical ChemistryTindescription
Abstract The ability of aromatic acid hydrazides, RCONHNH, to act as bidentate chelating agents towards diorganotin(IV) dichlorides has been investigated. The structure of the complexes were deduced from IR, NMR and Mossbauer spectroscopic techniques in combination with analytical data. The R2SnCI2.L complexes have octahedral geometry where the tin atom is chelated with one ligand (via carbonyl oxygen and hydrazinic nitrogen atoms), two chlorine atoms are in equatorial positions while the R groups are in the axial positions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-02-01 | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry |