Generation and transformation of the [3.3.1]propellane skeleton by thermal rearrangements

6533b838fe1ef96bd12a4f03

RESEARCH PRODUCT

Generation and transformation of the [3.3.1]propellane skeleton by thermal rearrangements

Guido Krämer Herbert Meier Heinz Kolshorn

subject

chemistry.chemical_classification Propellane chemistry.chemical_compound Flash vacuum pyrolysis chemistry Computational chemistry Organic Chemistry Drug Discovery Thermal Alkyne Photochemistry Biochemistry Transformation (music)

description

Abstract In a sequence of unexpected thermal rearrangements the strained monocyclic alkyne 4 is transformed into the tricyclic system 5 which yields in a flash vacuum pyrolysis again a monocyclic compound 10 .

year	journal	country	edition	language
1994-11-01	Tetrahedron Letters

https://doi.org/10.1016/s0040-4039(00)74405-4

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