6533b839fe1ef96bd12a58db

RESEARCH PRODUCT

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Gonzalo BlayPedroEmilio PardoGiménez TM. C. MuñozIsabel FernándezFrancesc LloretRafael Ruiz

subject

Alkanechemistry.chemical_classificationChemistryDimerMetals and Alloyschemistry.chemical_elementGeneral ChemistryCrystal structureManganeseCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundPolymer chemistryMaterials ChemistryCeramics and CompositesOrganic chemistryCarboxylate

description

A new manganese(III) oxamato dimer possesing an unprecedented Mn2(μ-O2CR)(μ-OH2⋯O2 CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by ButO2H and O2 in CH2Cl2 at rt.

https://doi.org/10.1039/b105132f