6533b839fe1ef96bd12a58e4
RESEARCH PRODUCT
Polymere ester von säuren des phosphors, 6. Ringöffnende polymerisation cyclischer phosphite und phosphonite durch michaelis-arbuzov-reaktion.–Theorie zur struktur der hauptkette
Walter Vogtsubject
chemistry.chemical_classificationchemistry.chemical_compoundMonomerchemistryPolymerizationInsertion reactionPolymer chemistryOrganic chemistryPolymerDynamic equilibriumdescription
The hypothesis of Harwood and Patel, suggesting for the polymerization of 2-phenyl-1,3,2-dioxaphospholane a type of insertion reaction to explain the formation of ethylenediphosphinic ester structures besides the normal 2-hydroxyethyl(phenyl)phosphonic ester structures is extended to similar monomers and its theoretical consequences are examined. It is shown that in such a system mutual transformations between ω-hydroxyalkyl-P-acid and alkylenedi(P-acid)structures should occur, establishing a dynamic equilibrium and leading to a sort of azeotropic polymer, in which only one unique composition is kinetically stable. Equations relating to different kinetic parameters are deduced.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1977-12-01 | Die Makromolekulare Chemie |