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RESEARCH PRODUCT
Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates
R. Alan HowieMark R. St J. ForemanEugenio CoronadoCarlos J. Gómez-garcíaJanet M. S. SkakleSusan A. McwilliamM. John Platersubject
chemistry.chemical_classificationHydrogen bondMetallurgychemistry.chemical_elementZincManganeseCrystal structureHydrothermal circulationDivalentlaw.inventionInorganic ChemistryCrystallographychemistrylawMaterials ChemistryComposition (visual arts)Physical and Theoretical ChemistryCrystallizationdescription
Abstract The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)3]·2H2O (1), [Mn(C8H4O5)(2,2′-bipy)]·H2O (2), [Mn2(C8H4O5)2(C8H7N3)2]·H2O (3) and [Zn(C8H4O5)(2,2′-bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2–4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2001-08-01 | Polyhedron |