6533b839fe1ef96bd12a6780
RESEARCH PRODUCT
Stereoselective Hydrosilylation of Enals and Enones Catalysed by Palladium Nanoparticles
Sakari TuokkoPetri M. PihkoMeryem Benohoudsubject
HydrosilylationOrganic ChemistryNanoparticlechemistry.chemical_elementAlcoholGeneral ChemistryHeterogeneous catalysisCatalysisCatalysisSolventchemistry.chemical_compoundchemistryOrganic chemistryStereoselectivityta116Palladiumdescription
A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1) enolsilanes of high isomeric purity, 2) saturated aldehydes or ketones, or 3) the corresponding saturated acetals from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-03-01 | Chemistry - A European Journal |