0000000000292136
AUTHOR
Meryem Benohoud
Organocatalytic α-Methylenation of Aldehydes: Preparation of 3,7-Dimethyl-2-Methylene-6-Octenal
4-(Dimethylamino)benzoic acid Pyrrolidine Citronellal 3,7-Dimethyl-2-methylene-6-octenal Formaldehdye, aqueous Keywords: Aldehydes. Methylenation; Organo catalytic reaction; Alpha-substituted acroleins; Intermediates; Rapid synthesis; Functionalities; Waste disposal
Stereoselective Hydrosilylation of Enals and Enones Catalysed by Palladium Nanoparticles
A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1) enolsilanes of high isomeric purity, 2) saturated aldehydes or ketones, or 3) the corresponding saturated acetals from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol.