0000000000292136

AUTHOR

Meryem Benohoud

showing 2 related works from this author

Organocatalytic α-Methylenation of Aldehydes: Preparation of 3,7-Dimethyl-2-Methylene-6-Octenal

2010

4-(Dimethylamino)benzoic acid Pyrrolidine Citronellal 3,7-Dimethyl-2-methylene-6-octenal Formaldehdye, aqueous Keywords: Aldehydes. Methylenation; Organo catalytic reaction; Alpha-substituted acroleins; Intermediates; Rapid synthesis; Functionalities; Waste disposal

chemistry.chemical_compoundAqueous solutionChemistryCitronellalOrganic chemistryMethylenePyrrolidineCatalysisBenzoic acidWaste disposal
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Stereoselective Hydrosilylation of Enals and Enones Catalysed by Palladium Nanoparticles

2011

A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1) enolsilanes of high isomeric purity, 2) saturated aldehydes or ketones, or 3) the corresponding saturated acetals from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol.

HydrosilylationOrganic ChemistryNanoparticlechemistry.chemical_elementAlcoholGeneral ChemistryHeterogeneous catalysisCatalysisCatalysisSolventchemistry.chemical_compoundchemistryOrganic chemistryStereoselectivityta116PalladiumChemistry - A European Journal
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