Analysis of an impedance function of zinc anodic dissolution

6533b83afe1ef96bd12a6f33

RESEARCH PRODUCT

Analysis of an impedance function of zinc anodic dissolution

Francisco Vicente José Juan García-jareño David Giménez-romero

subject

Aqueous solution Chemistry General Chemical Engineering Faradaic impedance Analytical chemistry chemistry.chemical_element Zinc Kinetic energy Analytical Chemistry Dielectric spectroscopy Reaction rate constant Transition metal Electrochemistry Electrical impedance

description

Zinc anodic dissolution has been studied by means of electrochemical impedance spectroscopy (EIS). The kinetic study of the oxidation mechanism has allowed us to propose a theoretical impedance function for this system in deaerated sulphate medium. Relevant information on the faradaic process is provided by analysis of the theoretical impedance function. Kinetic parameters of this system can be calculated from the fitting of experimental data to the faradaic impedance function deduced theoretically. The physical measurements of this function are analysed by means of the dependence of simulated EIS spectra on kinetic parameters.

year	journal	country	edition	language
2004-11-01	Journal of Electroanalytical Chemistry

https://doi.org/10.1016/j.jelechem.2003.09.029

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