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RESEARCH PRODUCT
Structure, properties and comparison of C,N-chelated and amido-stabilized plumbylenes
Zdeňka PadělkováPhilippe MeunierJaroslav HolečekJosef BarešAleš RůžičkaIvana CísařováVítězslav ŠOurekNadine Piriosubject
CrystallographyLigandChemistryX-ray crystallographySolid-stateMoleculeChelationGeneral Chemistrydescription
The molecular structure of {2-[(CH3)2NCH2]C6H4}2Pb (1) in the solid state was determined by X-ray diffraction techniques on a single crystalline material. Bulky amido ligand stabilized complexes [(i-C3H7)2C6H3]NHLi (2) and [(i-C3H7)2C6H3N(Me3Si)]2Pb (3) were synthesized and characterized both in the solid state and solution by 1H, 13C, 15N and 207Pb NMR and XRD techniques. The structure of both C,N-chelated and bulky amido plumbylenes is compared.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-01-01 | Collection of Czechoslovak Chemical Communications |