6533b83afe1ef96bd12a7b03
RESEARCH PRODUCT
Environmental NMR: Fast-field-cycling Relaxometry
Pellegrino ConteGiuseppe Alonzosubject
RelaxometryMolecular dynamicsField cyclingChemistryChemical physicsSoil porosityAnalytical chemistrySpin–lattice relaxationNMR relaxometry environmental field cycling spin–lattice relaxationNatural organic matterdescription
Fast-field-cycling (FFC) NMR relaxometry deals with the variation of the spin–lattice relaxation times (T1) in a complex system, as the strength of the applied magnetic field is changed. Information about molecular dynamics can be achieved. Until now, only model theories for FFC NMR relaxometry have been developed for polymer and material sciences. Just a few applications have been performed in the environmental sciences. These mainly deal with soil porosity, rock permeability, biomass transformations, and natural organic matter dynamics. Further, FFC NMR relaxometry can also be applied to monitor the environmental fate of contaminants, to understand the dynamics of nutrients at the soil–plant interface, and to evaluate reaction mechanisms in heterogeneous catalysis for the development of green reactions. This article summarizes the advances of the technique in environmental investigations and describes the tools used to monitor dynamics of organic and inorganic molecules in environmental compartments.
year | journal | country | edition | language |
---|---|---|---|---|
1996-03-06 |