6533b851fe1ef96bd12a8bcb
RESEARCH PRODUCT
Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization
Nicolas DesboisValentin QuesneauClaude P. GrosKarl M. KadishWenqian ShanVirginie Blondeau-patissierStéphane BrandèsE. Van CaemelbeckeE. Van CaemelbeckeWilliam Ryan OsterlohXiaoqin Jiangsubject
010405 organic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistryElectrochemistry01 natural sciencesRedoxCatalysis0104 chemical sciencesAdductchemistry.chemical_compoundchemistryPyridinePolymer chemistryMaterials ChemistryCobaltCarbon monoxidedescription
Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-01-01 | New Journal of Chemistry |