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RESEARCH PRODUCT
Synthesis and Topological Determination of Hexakis-Substituted 1,4-Ditritylbenzene and Nonakis-Substituted 1,3,5-Tritritylbenzene Derivatives: Building Blocks for Higher Supramolecular Assemblies
Martin NiegerAndreas HafnerAlexandra SchadeThierry MullerJuhani HuuskonenKari RissanenStefan BräseOliver Plietzschsubject
Substitution reaction010405 organic chemistryStereochemistryOrganic ChemistrySupramolecular chemistry010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical scienceschemistry.chemical_compoundchemistryPhysical and Theoretical ChemistryFamily basedMesitylenedescription
Based on trityl moieties, novel organic building blocks have been prepared and structurally investigated. Substituted hexaphenyl-p-xylene (1,4-ditritylbenzene) as well as extended analogues thereof were prepared. Furthermore, a new family based on a 1,3,5-tritritylbenzene motif, connecting three trityl groups through a formal mesitylene unit, was developed. Both families were further converted through six- and nine-fold substitution reactions, respectively, to yield potent molecular building blocks for supramolecular assemblies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-11-27 | European Journal of Organic Chemistry |