Cellulose-click-ferrocenes as docking spots for cyclodextrin

6533b851fe1ef96bd12a8cd6

RESEARCH PRODUCT

Cellulose-click-ferrocenes as docking spots for cyclodextrin

Robert Branscheid Beate Mondrzik Helmut Ritter Berit Knudsen Ute Kolb

subject

chemistry.chemical_classification Materials science Polymers and Plastics Cyclodextrin Organic Chemistry Cycloaddition law.invention Microcrystalline cellulose chemistry.chemical_compound Ferrocene chemistry Dynamic light scattering law Polymer chemistry Materials Chemistry Click chemistry Electron microscope Cellulose

description

A novel synthesis of ferrocene-modified cellulose, prepared from 6-azido-6-deoxy-cellulose and ethynylferrocene, is presented. The two components were coupled via copper-catalyzed click-type cycloaddition under microwave-assisted conditions. The surface structure of the cellulose derivative was investigated in comparison with that of pure, microcrystalline cellulose using electron microscopy (scanning, transmission and scanning transmission), showing iron atoms of ferrocene as homogeneously distributed particles. They are detectable as clear signals in the energy-dispersive X-ray profile. In addition, Rame-β-cyclodextrin was supramolecularly attached to cellulose and the complex formed was studied by use of 2D ROESY NMR and dynamic light scattering. Copyright © 2012 Society of Chemical Industry

year	journal	country	edition	language
2012-05-04	Polymer International

https://doi.org/10.1002/pi.4225

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