6533b851fe1ef96bd12a8ce8

RESEARCH PRODUCT

Cycloalkin-vinylidencycloalkan-umlagerungen

Markus SchmittHerbert Meier

subject

chemistry.chemical_classificationAlleneOrganic ChemistryConjugated systemRing (chemistry)PhotochemistryBiochemistryMedicinal chemistrychemistry.chemical_compoundHydrocarbonchemistryDrug DiscoveryIsomerizationPyrolysis

description

Abstract Flash pyrolysis of the strained cyclic alkynes 1 leads to ring systems 2 with an exocyclic allene group and in a further isomerization step to the conjugated vinyl compounds 3 .

https://doi.org/10.1016/s0040-4039(01)93493-8