6533b851fe1ef96bd12a8d86

RESEARCH PRODUCT

Photocatalytic oxidation of trans-ferulic acid to vanillin on TiO2 and WO3-loaded TiO2 catalysts

Bartolomeo MegnaAgatino Di PaolaLeonardo PalmisanoMarianna BellarditaFrancesco Parrino

subject

chemistry.chemical_classificationSettore ING-IND/24 - Principi Di Ingegneria ChimicaVanillin synthesiWO3-loaded TiO2 photocatalystsVanillinInorganic chemistryTrans-ferulic acid oxidationGeneral ChemistryAldehydeTungsten trioxideCatalysislaw.inventionCatalysisFerulic acidchemistry.chemical_compoundPhotocatalysiSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistrylawPhotocatalysisCalcinationSettore CHIM/07 - Fondamenti Chimici Delle TecnologieSelectivity

description

Abstract The photocatalytic oxidation of trans-ferulic acid to vanillin in water has been studied by using various TiO2 and WO3-loaded TiO2 samples as catalysts. Different values of selectivity were obtained depending on the physico-chemical properties of the single samples and a vanillin selectivity of 10% was reached in the presence of the commercial TiO2 Merck. Higher selectivity values were obtained by impregnation of TiO2 with H2WO4 followed by calcination. The increased production of vanillin exhibited by the obtained WO3-loaded TiO2 powders was attributed to a reduced further oxidation of the aldehyde caused by the presence of the practically inactive tungsten trioxide hydrate on the TiO2 surface. The best result (ca. 25% of selectivity) was obtained with the WO3(1%)/TiO2 sample.

yearjournalcountryeditionlanguage
2015-09-01Catalysis Today
https://doi.org/10.1016/j.cattod.2014.09.012