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RESEARCH PRODUCT

Effects of anodizing surface treatment on the mechanical strength of aluminum alloy 5083 to fibre reinforced composites adhesive joints

Monica SantamariaAntonino ValenzaD. BadagliaccoF. Di FrancoVincenzo FioreR. Miranda

subject

Materials sciencePolymers and PlasticsGeneral Chemical EngineeringAlloychemistry.chemical_element02 engineering and technologyengineering.materialCorrosionBiomaterials03 medical and health scienceschemistry.chemical_compound0302 clinical medicineAluminiumUltimate tensile strengthAluminium alloyComposite materialAnodizingtechnology industry and agriculture030206 dentistryEpoxy021001 nanoscience & nanotechnologySilaneSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiSettore ING-IND/23 - Chimica Fisica Applicatachemistryvisual_artAdhesive joint Anodizing Basalt Corrosion resistance Silane coupling agent Surface treatmentvisual_art.visual_art_mediumengineering0210 nano-technology

description

Abstract In this study, the anodizing process based on the use of tartaric sulfuric acid solution (TSA) was carried out on metal substrate to evaluate for the first time its effect on the adhesion strength and corrosion resistance of aluminium alloy (i.e., AA5083) to fibre (i.e., basalt or glass) reinforced composite adhesive joints for nautical applications. Furthermore, some TSA anodized samples were soaked in a NaOH solution to investigate the influence of this post-immersion step on the joint performances. With the aim to improve the fibre-matrix adhesion in the composite substrate thus further increasing the overall mechanical response of the joint, glass and basalt fibres were treated with a silane coupling agent solution. The corrosion behaviour of the aluminium alloy was studied by electrochemical techniques. Samples morphology was analysed by scanning electron microscopy, while the interaction between aluminium alloy substrate and epoxy resin was studied through contact angle analysis and resin uptake tests. The effectiveness of the silane treatment was examined by means of Fourier transform infrared spectroscopy and quasi-static tensile tests carried out on dry glass and basalt fabrics. The mechanical response of the resulting joints was evaluated by means of quasi-static tensile tests in accordance to ASTM D3528 standard.

https://doi.org/10.1016/j.ijadhadh.2021.102868