6533b852fe1ef96bd12aac99

RESEARCH PRODUCT

Assembly of a planar, tricyclic B4N8 framework with s-indacene structure.

Heikki M. TuononenHanh V. LyMasood ParvezRoland Roesler

subject

Biphenylchemistry.chemical_classificationChemistryMetals and AlloysBoranesGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundPlanarComputational chemistryMaterials ChemistryCeramics and CompositesOrganic chemistryTricyclic

description

A neutral, formally 16pi-electron, tricyclic tetrahydrazidotetraborane was obtained in a two-step procedure involving self-assembly of a dilithiodiborate with B(4)N(8) framework and subsequent oxidation of the phenylborate moieties to boranes and biphenyl using Fe(II) as an oxidant.

10.1039/b709270ahttps://pubmed.ncbi.nlm.nih.gov/17971976