EPR of molybdenum-related defect in CdWO4 crystal

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EPR of molybdenum-related defect in CdWO4 crystal

subject

Radiation Chemistry chemistry.chemical_element Crystal structure Resonance (chemistry)Crystallographic defect Spectral line law.invention Crystal Crystallography Nuclear magnetic resonance law Molybdenum Electron paramagnetic resonance Luminescence Instrumentation

description

Abstract EPR spectra of a molybdenum-related structure defect have been observed at a temperature of 20 K in CdWO 4 scintillator crystal, being as-grown “blue-coloured”. Mo 95 and Mo 97 isotope superhyperfine ( shf ) splittings have been resolved. Further splittings in EPR spectra have been interpreted as arising from shf interactions with W nuclea. In the present model of the defect, the unpaired spin is localised in the Cd-site position and molybdenum replaces one of the neighbouring W atoms.

year	journal	country	edition	language
1998-05-01	Radiation Measurements

https://doi.org/10.1016/s1350-4487(98)00027-4

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