6533b853fe1ef96bd12ac17e

RESEARCH PRODUCT

Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity

José Antonio RealLucía Piñeiro-lópezM. Carmen MuñozMaksym Sereduk

subject

StereochemistryMetals and AlloysOne-StepGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsNitrobenzeneCrystallographychemistry.chemical_compoundchemistrySpin crossoverFISICA APLICADAMössbauer spectroscopyMaterials ChemistryCeramics and CompositesSpin (physics)Naphthalene

description

Structural, magnetic, calorimetric and Mo¨ssbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel FeII Hofmann-like porous metal–organic framework {Fe(bpb)[Pt(CN)4]}2Guest are described (bpb = bis(4-pyridyl)butadiyne).

https://doi.org/10.1039/c3cc48595a